Article
PROSPECTS OF NANOTECHNOLOGY OF THE XXI CENTURY FOR CREATION OF CLIMATE-RESISTANT AND ENVIRONMENTALLY CLEAN TRANSPORT INFRASTRUCTURE
R. Asmatulayev
Associate Professor | Kazakh Automobile and Road Institute | ruslan_asmatulaev@mail.ru
N. Asmatulayev
Technical Director | KRDI "Dortrans" LLP | activ-cz@mail.ru
B. А. Asmatulayev
доктор технических наук, почетный профессор МАДИ, Академический советник Национальной инженерной академии РК, директор по науке ТОО НИ ПК «Каздоринновация» | ТОО НИ ПК «Каздоринновация» | boris-aisa@mail.ru
Keywords
Abstract
The article presents the results of fundamental laser research, experimental work and long-term monitoring of highways built using concrete based on belite road cements. Belite cements, containing predominantly two-calcium silicates (C2S-belite 50-80%), ensure a service life of road concrete of up to 50 years without the need for repairs. Laser studies have revealed the structure of belite cement stone, formed by nano-sized new formations known as colloidal calcium hydrosilicates CSH, promoting almost complete hydration of cement grains.
List of used literature: 1. Kochetkov A.V., Kokodeeva N.V., Rapoport P.B., Rapoport N.V., Shashkov I.G. Calculation and design of road pavements // Automobile roads. – 2011. – No. 12. – pp. 86-94 [Kochetkov AV, Kokodeeva NV, Rapoport PB, Rapoport NV, SHashkov IG Raschet i konstruirovanie dorozhnyh odezhd // Avtomobil'nye dorogi. – 2011. – No. 12. – S. 86-94]
2. Radovsky B.S. The concept of timeless travel clothes. Directory catalog: Road equipment. – 2011. – P. 120-132 [Radovskij BS Koncepciya vechnyh dorozhnyh odezhd. Katalog-spravochnik: Dorozhnaya tekhnika. – 2011. – S. 120-132.]
3. Gorelyshev N.V. Asphalt concrete and other bitumen and mineral materials. Mozhaisk-Terra, 1995. – P. 176. [Gorelyshev NV Asfal'tobeton i drugie bitumomineral'nye materialy. Mozhajsk-Terra, 1995. – S. 176.]
4. Asmatulaev B.A., Sheinin A.M., Chumachenko V.I. and others. Rolled concrete based on slag binder // Automobile roads. – 1993. – No. 9. – P. 18-20. [Asmatulaev BA, SHejnin AM, CHumachenko VI i dr. Ukatyvaemyj beton na osnove shlakovogo vyazhushchego // Avtomobil'nye dorogi. – 1993. – No. 9. – S. 18-20.]
5. Innovative patent No. 29852 RK. Self-healing road concrete / Asmatulaev B.A. and others. Publ. 05/15/15, bulletin. No. 5. [Innovacionnyj patent No. 29852 RK. Samovosstanavlivayushchijsya dorozhnyj beton / Asmatulaev BA i dr. Publ. 05.15.15, byul. No. 5.]
6. Taylor H.F. Calcium hydrosilicates. Chemistry of cement. – M.: Stroyizdat, 1969. – P.17-18. [Tejlor HF Gidrosilikaty kal'ciya. Himiya cementa. – M.: Strojizdat, 1969. – S.17-18.]
7. Ablanov B.F., Belousov B.V., Asmatulaev B.A. Study of the material composition and hardening kinetics of binders based on phosphorus slag. Issues of metallogeny, material composition and geological structure of deposits in Kazakhstan. – Almaty, 1978, Issue. 13. – pp. 69-75. [Ablanov BF, Belousov BV, Asmatulaev BA Issledovanie veshchestvennogo sostava i kinetiki tverdeniya vyazhushchego na osnove fosfornogo shlaka. Voprosy metallogenii, veshchestvennogo sostava i geologicheskogo stroeniya mestorozhdenij Kazakhstan. – Almaty, 1978, Vyp. 13. – S. 69-75.]
8. F. Sanchez, L. Zhang, C. Ince.Multi-scale performance and durability of carbon nanofiber/cement composites. In: Bittnar Z, Bartos PJM, Nemecek J, Smilauer V, Zeman J, editors. Nanotechnology in construction: proceedings of the NICOM3 (3rd international symposium on nanotechnology in construction). Prague, Czech Republic; 2009, p. 345–50.
9. H. M. Jennings, J. W. Bullard, J. J. Thomas, J. E. Andrade, J. J. Chen, G. W. Scherer.Characterization and modeling of pores and surfaces in cement paste: correlations to processing and properties. J Adv Concr Technol 2008; 6(1):5–29.
10. F. Sanchez, A. Borwankar.Multi-scale performance of carbon microfiber reinforced cementbased composites exposed to a decalcifying environment Mater Sci Eng A 2010; 527(13–14): 3151–8.
11. K. P. Chong, E. J. Garboczi.Smart and designer structural material systems [Intelligent and design systems of structural materials]. Prog Struct Mat Eng 2002; 4:417–30.16.E. J. Garboczi, D.P.Structure of calcium silicate hydrate [Solubility and structure of calcium silicate]. Cem Concr Res 2004; 34(9): 1499–519.
12. K. Sobolev.Mechano-chemical modification of cement with high volumes of blast furnace slag [Mechano-chemical modification of cement with high content of blast furnace slag]. Cem Concr Compos 2005; 27(7–8):848–53.
13. J. Minet, S. Abramson, B. Bresson, A. Franceschini, H. Van Damme, N. Lequeux.Organic calcium silicate hydrate hybrids: a new approach to cement based nanocomposites. J Mater Chem 2006; 16:1379–83.
14. A. Franceschini, S. Abramson, V. Mancini, B. Bresson, C. Chassenieux, N. Lequeux.New covalent bonded polymer–calcium silicate hydrate composites [New covalently bonded polymer-calcium hydrosilicate composites]. J Mater Chem 2007; 17:913–22.
15. H. Matsuyama, J. F. Young.Intercalation of polymers in calcium silicate hydrate: a new synthetic approach to biocomposites. [Introduction of calcium hydroxide silicate polymers: a new synthetic approach to biocomposites.] Che m Mater 1999; 11:16–9.
16. Patent No. 4110 for utility modelRK. Design of road pavement based on nanomodified concrete / Asmatulaev B.A., Asmatulaev R.B., Chumachenko V.I., Asmatulaev N.B., Mazgutov R.A., Amankosov Zh.A., Ezmahunov R.R. Publ. 2019. Bull. No. 26. [Patent na poleznuyu model' 4110 RK. Konstrukciya dorozhnoj odezhdy na osnove nanomodificirovannogo betona / Asmatulaev BA, Asmatulaev RB, CHumachenko VI, Asmatulaev NB, Mazgutov RA, Amankosov ZH.A., Ezmahunov RR Publ. 2019. Byul. No. 26.]
17. Provisional patent No. 16413RK. Sulfur asphalt concrete mixture / Asmatulaev B.A., Nadirov N.K., Asmatulaev R.B., Pshembaev M.K. and others. Publ. 2005. Bulletin. No. 11. [Predvaritel'nyj patent No. 16413 RK. Seroasfal'tobetonnaya smes' / Asmatulaev BA, Nadirov NK, Asmatulaev RB, Pshembaev MK i dr. Publ. 2005. Byull. No. 11.]
18. PatentNo. 6701 RK. Nanostructuring mineral powder and nanostructured asphalt concrete / Asmatulaev B.A., Asmatulaev R.B., Chumachenko V.I., Asmatulaev N.B., Islamov V.A. Bessonov D.V.Publ.2021. . Bull. No. 16. [Patent No. 6701 RK. Nanostrukturiruyushchij mineral'nyj poroshok i nanostrukturirovannyj asfal'tobeton / Asmatulaev BA, Asmatulaev RB, ChumachenkoVI, Asmatulaev NB, Islamov VA Bessonov DV Publ. 2021. Byul. No. 16.]
19. Patent No. 30948 RK. Warm or cold asphalt concrete mixture (variants) / Asmatulaev B.A., Asmatulaev R.B., Tursumuratov M.T., Islamov V.A., Amirkhanov Zh.A., Asmatulaev N.B.Publ.2016. Bulletin No. 3. [Patent No. 30948 RK. Teplaya ili holodnaya asfal'tobetonnaya smes' (varianty) / Asmatulaev BA, Asmatulaev RB, Tursumuratov MT, Islamov VA, Amirhanov ZH.A., Asmatulaev NB Publ. 2016. Byul.№3.]
20. Utility model patent No. 3607 RK. Complex polymer dispersed reinforcing additive / Asmatulaev B.A., Asmatulaev N.B., Amirkhanov Zh.A., Bessonov D.V.Publ.2018. [Patent on poleznuyu model' No. 3607 RK. Kompleksnaya polimernaya dispersno-armiruyushchaya dobavka / Asmatulaev B.A., Asmatulaev N.B., Amirhanov Z.H.A., Bessonov D.V. Publ. 2018.]